diff --git "a/H9AzT4oBgHgl3EQfHvt9/content/tmp_files/2301.01050v1.pdf.txt" "b/H9AzT4oBgHgl3EQfHvt9/content/tmp_files/2301.01050v1.pdf.txt" new file mode 100644--- /dev/null +++ "b/H9AzT4oBgHgl3EQfHvt9/content/tmp_files/2301.01050v1.pdf.txt" @@ -0,0 +1,2044 @@ +Geometric theory of topological defects: methodological +developments and new trends +Sébastien Fumeron‡, Bertrand Berche‡, and Fernando Moraes† +‡Laboratoire de Physique et Chimie Théoriques, +UMR Université de Lorraine - CNRS 7019, 54000 Nancy, France and +†Departamento de Física, Universidade Federal Rural +de Pernambuco, 52171-900, Recife, PE, Brazil +Abstract +Liquid crystals generally support orientational singularities of the director field known as topo- +logical defects. These latter modifiy transport properties in their vicinity as if the geometry was +non-Euclidean. We present a state of the art of the differential geometry of nematic liquid crystals, +with a special emphasis on linear defects. We then discuss unexpected but deep connections with +cosmology and high-energy-physics, and conclude with a review on defect engineering for transport +phenomena. +1 +arXiv:2301.01050v1 [cond-mat.soft] 3 Jan 2023 + +I. +INTRODUCTION +One of Pierre-Gilles de Gennes’s greatest breakthrough was to realize that methods and +concepts borrowed from superconductivity also apply to describe smectic-A phases [1]. His +work is a striking example of cross-fertilization between different areas of physics and it +highlights how progress arises at the crossroads of various scientific fields. In an article +that has not been translated in English [2], he took the example of line singularities as a +common denominator between liquid crystals, quark physics and superconductors [3]. The +same observation was also made by William Brinkman and Patricia Cladis [4], and most +notably by the two-Nobel-Prize winner John Bardeen in a review written as a plea for +interdisciplinarity: “Line defects in three-dimensional systems, quantized vortex lines or flux +lines, and dislocations account for similarities of behavior in superconductors, liquid crystals, +and, it is hoped, color confinement of quarks“[5]. +In this spirit, the objective of this paper is to perform an in-depth survey of geometrical +methods useful for investigating topological defects and to describe some of its modern +applications, either as a playground to test fundamental ideas in high-energy physics or +gravitational physics, or as high-performance tools to taylor transport phenomena from soft +matter devices. We will be mainly concerned with nematic liquid crystals and topological +line defects. +In section II, we provide a self-contained introduction to phase transitions, geometry, +topology and optics in such systems. We show how a metric description of defect lines in +terms of Riemann manifolds naturally arises in nematics, before addressing the question of +analogue gravity which may be less familiar to the liquid crystals community. +Section III is an introduction to some of the ideas borrowed to cosmology which can +be dealt with liquid crystals, such as the Kibble mechanism, which rules the formation of +defects in the early universe but also in nematics. We review several outstanding problems +involving line singularities, such as cosmic strings, wormholes and bouncing cosmologies, +and discuss their connections with disclinations in liquid crystals. +Section IV eventually discusses applications of the geometric formalism previously in- +troduced for the description of acoustics, optics and heat transfer in the presence of such +defects. The main idea is to show how the curvature carried by the topological defects +can be used to design specific propagation patterns, a possible step forward towards the +2 + +defect-engineering of transport phenomena. +II. +TOPOLOGICAL DEFECTS IN NEMATIC LIQUID CRYSTALS +A. +Basics of the isotropic-nematic phase transition +a. +Historical milestones +The story of liquid crystal has met with a shaky start. The +first observations reported of what is today understood as a liquid crystal belong to the +realm of biology. Georges-Louis Buffon (1707-1788) and later Rudolf Virchow (1854) and +Carl Mettenheimer (1855) reported about the strange behavior of lecithins, a family of +phospholipid substances contained in plants (wheat, rye...) and in animals (yolks, myelin +- the insulating coating of nerve fibres - ...) [6]. When suspended in water, lecithins form +birefringent tubular structures like a Iceland spar but that writhed like eels. Julius Planer +in 1861 [7] and most importantly Friedrich Reinitzer in 1888 discovered similar optical +behaviors with cholesterol compounds. Reinitzer extracted cholesteryl esters from carrots +and made an unanticipated observation: contrary to what was known in crystallography, +cholesteryl benzoate displays two melting points [8]. The lower one occurs at about 145.5◦C +and correspond to the melting of the solid phase into a turbid fluid. The higher melting +point corresponds to the clarification of the milky liquid beyond 178.5◦C. +Such behavior left Reinitzer skeptical: had he discovered a genuinely new behavior of +matter or was this simply the result of impure and incompletely melted crystals? Reinitzer +wrote to Otto Lehmann, a leading physicist known for designing the first “crystallization +microscope”: this latter consists in a microscope equipped with crossed polarizers and a +thermal deck (a small Bunsen burner and two cooling blasts) to observe how crystals behave +when the temperature varies. Lehmann reproduced and improved Reinitzer’s observations, +and promoted these substances as new forms of matter, half-between liquids and crystals. In +1889, he coined the term “liquid crystals” to account for his discovery (somehow pulling the +sheet back towards him as he even claimed priority over Reinitzer [9]). Soon afterwards, he +kept changing its name (including “flowing crystals”, “crystalline liquids”...), which reveals +his difficulties to grasp the real nature of what he found. +The years that followed Lehmann’s breakthrough have been critical. On one hand, the +subject became more and more discussed in the scientific community, even drawing the +3 + +attention of future Nobel Prize laureates such as Max Born (in 1916, he conceived the +first molecular theory of liquid crystals but predicted a generic ferroelectric behavior that +turned out to be incorrect [10]), Jacobus Henricus van’t Hoff and Walther Nernst (Lehmann +himself was an unlucky nominee from 1913 to 1922). On the other hand, the subject became +highly controversial: partly because Nernst and most especially Gustav Tammann led a +vivid opposition against liquid crystals (suspecting them of being nothing more than poorly +prepared colloidal mixtures), partly because of Lehmann’s personality (a sparkling mix of +pretentiousness and mysticism [9]). +Liquid crystals have stayed a controversial subject, since the decisive contributions of +Rudolf Schenk (1905), Daniel Vorländer (1907) and George Friedel (1922) to get a clear view +on this subject. Schenk led a thorough study of the clearing point and unambiguously showed +the observed properties (density, viscosity) could not be related to mixtures. +Vorländer +elucidated the mysterious anisotropic behavior exibited by the fluid: from a microscopic +standpoint, liquid crystals consist in self-organized assemblies of rod-like molecules. +As +such, they exibit both the birefringence property expected from anisotropic uniaxial media +and the ability to flow. Finally, Friedel realized that such substances should properly be +understood as new full-blown phases of matter, that he named mesophases. Initially divided +into three broad families (nematic, cholesteric and smectic), liquid crystals have now been +enriched by many new mesophases, including columnar phases, cubatic phases, blue phases +I, II and III... +b. +Mesogenic behavior +The recipe for a molecule to be nematogenic (i.e. to have the +ability to organize into a nematic phase) is rather simple: take a rod-like molecule and deck +it with 1) a flexible outer part (an aliphatic chain), 2) a rigid core (phenyl groups most +generally) and 3) a chemical group bearing a permanent dipole (for instance, a carbonitrile +group as in 5CB). The resulting substance is a thermotropic nematic, a sensitive compromise +between the attractive Van der Waals interactions that align rigid cores on average along the +same direction (anisotropy) and the thermal agitation of the aliphatic chains increasing the +mean steric hindrance (fluidity). Nematics can also be lyotropic: the nematogens display +an amphiphilic structure (they have both hydrophilic and hydrophobic parts), the control +parameter being the concentration of molecules in a solvent such as water. The frontier +between thermotropic and lyotropic liquid crystalline behavior being not strict, nematogens +can also behave as amphotropic media. +4 + +In the perspective of section III, let us focus on thermotropic nematics. In that case, there +are different models accounting adequately for the phase transition. The Lebwohl-Lasher +model [11] is the paradigmatic model in this context, in a sense the liquid crystal analogue +of the Ising model [12]: the nematogen molecules are represented only by their direction and +they occupy fixed positions on the sites of a cubic lattice. The different sites of the lattice +interact only between nearest neighbors through a potential that favors configurations where +the neighboring molecules point in the same direction. On the contrary, the Maier-Saupe +approach is a mean-field theory: interactions between particles are replaced by an effective +field experienced by all particles at the same time. This model considers only London forces +between instantaneous molecular dipoles and ignores repulsive interactions [13]. This also +favors alignment of the molecules in the same direction. We will briefly mention that for +lyotropic nematics, Lars Onsager described the phase transition of an assembly of rod-like +sticks as an entropic process driven [14]: due to purely steric effects, orientational entropy +loss is more than offset by positional entropy gain which triggers the transition. +Depending on the temperature range, three (or more) phases can be observed. At low +temperatures, the steric hindrance of aliphatic chains is minimal and the nematogens get +close enough for attractive forces to drive the system. As the dipole-dipole interactions +prevail over thermal agitation, the assembly of rod-like molecules organize into a molecular +crystal. This latter displays both a positional and rotational order for each molecule. On +the contrary, at high temperatures, Van der Waals interactions are dominated by thermal +effects and the nematogens form an isotropic fluid phase: both positional and orientational +order are lost. Within the intermediate range of temperature, the two effects are of the same +order and different kinds of mesophases may appear. In the nematic mesophase, only the +orientational order is preserved: locally, the nematogens tend to align on average along a +common direction, which defines the director field n. In usual nematics, the orientational +order is preserved at long distance, as the correlation length is typically about a few µm, +compared to the nematogen length around a few nanometers. +As the phase transition +involves nucleation, these domains wherein nematogens share a common orientation form +submicronic bubbles (or spherulites). Then they grow in size and eventually they meet and +mingle, sometimes leaving relics in the form of long threads. +c. +Order parameter +Within a nematic, a particular molecule does generally not point +exactly in the direction n and the degree of orientational ordering of the mesophase can thus +5 + +be assessed by looking how well the nematogens are aligned along the director field. The +quadrupolar scalar order parameter S defined by Tsvetkov (1942) provides a quantitative +criterion to characterize the nematic order: it is normalized (S = 0 in the isotropic fluid phase +and S = 1 for perfectly aligned rods), and ranges from 0.3 < S < 0.8 in usual nematics (in +practice, 0.3 < S < 0.4 for thermotropic liquid crystals, whereas 0.6 < S < 0.8 for lyotropic +ones). The order parameter can be refined to include informations on the local orientation +of n (Landau – de Gennes tensorial order parameter) or to encompass phase involving more +complex-shaped mesogens (higher-order mutipole-multipole correlation functions). +For thermotropic nematics, S can be taken as a function depending only on the temper- +ature. The behavior of S at the transition can essentially discriminate between two main +families of phase transitions (in the sense defined by Lev Landau in 1937 [15]): first-order +phase transitions, for which the order parameter displays a jump at the transition control +parameter (this class also involves latent heats and nucleation processes), and second-order +phase transitions, for which the order parameter varies continuously at the transition (this +class involves pretransitional effects and scaling behaviors). Experimentally, for most com- +pounds (5CB, MBBA, 5CN...), the isotropic-nematic phase transition is identified as weakly +first-order phase transition in three dimensions. It combines small discontinuities of S [16], +nucleation [17] and low latent heats [18], but pretransitional effects of the dielectric proper- +ties [18]. +B. +From symmetry to topology +a. +Homotopy theory +The existence of orientational and/or positional orders impart +each phase about the transition with a specific set of symmetries. As a rule, the higher- +temperature phase is generally the less-ordered one and its symmetry group is larger. In +the isotropic-nematic case, the isotropic fluid phase and the nematic liquid crystal are both +statistically invariant under any translation in space. But for the orientational part, the +two phases do not share the same symmetry group. Indeed, the isotropic fluid phase is +statistically invariant under any rotation in three dimensions, that is, under the elements of +the group SO(3), while in the mesophase the director field plays the role of a symmetry axis, +restricting the symmetry to statistical invariance under the elements of the group SO(2). +But for energetic reasons, the dipoles borne by the nematogens tend to align anticollinear, +6 + +such that the assembly of rods is unchanged when inverting heads and tails (this dimeric +structure was confirmed early by X-ray diffraction experiments in 5CB and 7CB [19]). Hence, +the full symmetry group of the nematic phase is O(2). +Many important features of a phase transition with a spontaneous symmetry-breaking +are encompassed within the topology of an abstract object, called the order parameter space +M. For a phase transition with a symmetry-breaking pattern G → H, the order parameter +space is a manifold defined from the coset M = G/H. The toolbox of algebraic topology +(Poincaré’s former analysis situs) can then be used to seek the algebraic invariants (numbers, +groups, rings. . . ) of M and to classify this space into equivalence classes. +Among the many entry points, homotopy theory is of particular interest to determine the +presence of singularities. Two topological spaces are homotopic if they can be mapped into +each other by a continuous deformation where bijectivity is not necessarily preserved (i.e. +gluing, shrinking or fattening the space is allowed). Homotopy groups, denoted generically +as πk(M), have been extensively studied in condensed matter physics, mainly in the pio- +neering works of Kleman, Lavrentovich, Michel, Toulouse and Volovik [20–26] and they are +associated to different kinds of topological properties for M. For instance, π1(M) tests the +simple-connectedness of the order parameter space. Indeed, consider first M = R × R. It +is simply-connected as all closed loops (dimension 1) are homotopic to a point (dimension +0): therefore π1(M) = I and the order parameter space is simply connected. Conversely, +for M = R∗ × R∗, there are two equivalence classes of closed loops: those not encircling +the origin, which are homotopic to a point, and those encircling the origin which cannot be +shrunk into a point. Therefore π1(M) ̸= I and the order parameter space is not simply con- +nected. The 0D-hole has thus changed the homotopy content of π1(M). Interestingly, the +dimensionality of the manifold is crucial here: a loop trying to lasso a 0D-hole can succeed in +2D but will always fail in 3D. In its most general form, the fundamental result of homotopy +analysis states that in dimension n, if the k th homotopy group πk(M) ̸= I, then holes of +dimension n − 1 − k appear: such singularities are called topological defects. Strictly speak- +ing, a defect is topological when the singular configuration of the order parameter cannot +be transformed continuously into a uniform configuration. This process depends not only +on the order parameter configuration but also on the dimensionality of the order parameter +space (due to the possibility to “escape in the third dimension”). Therefore, there is also a +more flexible use for the terminology “topological defect”, referring to the singularity asso- +7 + +ciated to any non-trivial homotopy content of the order parameter manifold, whatever its +topological stability is. In the remainder of this article, we will stick to that latter meaning. +b. +Zoology of topological defects in nematics +For the isotropic-nematic phase, the order +parameter space is given by M = SO(3)/O(2) ≡ S2/Z2: the resulting space, called the real +projective plane RP 2, can be pictured as a 2-sphere having its antipodal points identified. +The manifold corresponding to an immersion of the real projective plane in 3D space is +called a Boy surface and its topology is encompassed into its first four homotopy groups: for +uniaxial nematics in 3D, these are π0(RP 2) = I (no domain wall), π1(RP 2) = Z2 (existence +of linear defects), π2(RP 2) = Z (existence of point defects) and π3(RP 2) = Z (existence of +textures). +FIG. 1. Left: Class N = 0 of closed loops homotopic to a point in the order parameter space. +Right: Class N = 1 of closed loops consisting of paths connecting two antipodal points, which are +not homotopic to a point. +Linear defects (or “disclinations” in Frank’s terminology) come from a breaking of the ro- +tational symmetry group and they are probably the most widespread singularities observed +in nematics. In optical microscopy, they appear as thread-like structures used by Friedel to +coin the term nematic (from the greek νηµα="thread"). In polarizing microscopy, disclina- +tions give rise to the beautiful Schlieren patterns, where dark brushes connect at singular +8 + +A'=A +O +T,(RP2)=Z2=[0,1) +unstable +stablepoints corresponding to the line defects viewed end on. The content of the first homotopy +group (or Poincaré group) is Z2 = 0, 1, which means that there are two equivalence classes +for closed loops. The trivial class N = 0 corresponds to defects that are not topologically +stable (they can relax into a uniform configuration), whereas the second non-trivial class +N = 1 corresponds to defects that cannot be removed (see Fig. 1). For reasons we will +clarify later, we retain the terminology of wedge disclinations to the trivial class and the +terminology of Mœbius disclinations to the non-trivial class. A disclination can stay almost +straight or form loops. It is generally associated to other disclinations within dipoles (edge +dislocations), amorphous networks (blue phases), etc. In that case, they have the possibility +to interconnect [27] and they combine according to the algebra of Z2, that is 0 + 0 = 0, +0 + 1 = 1 and 1 + 1 = 0. An extensive review on linear defects in the general context of ill- +ordered condensed matter can be found in [28]. Since our main concern here is disclinations +we refer the reader interested in point defects and textures (including the exotic skyrmions +and hopfions) to the the very complete reviews [17] and [29], respectively. +C. +Optics in the presence of linear defects +a. +Director field of axial disclinations +A region characterized by a given director field +can undergo orientational distorsions as a result of external constraints. As n is a unit +(headless) vector, the distorsions always occur in a plane orthogonal to the director field, +i.e. δn.n = 0. From a Taylor expansion, one can rewrite the deformed state as the sum of +three main elastic modes: a splay term in ∇.n, a twist term in n.(∇ × n) and a bend term +in |n × (∇ × n)|. The Frank-Oseen free energy density is the elastic cost of orientational +oscillations around n: +fV = 1 +2K1(∇.n)2 + 1 +2K2(n.(∇ × n))2 + 1 +2K3(n × (∇ × n))2. +(1) +Equilibrium state corresponds to configurations such that fV is extremal. Elastic constants +are of order E0/L, with the interaction energy about E0 ≈ 0.1 eV and L ≈ 1 nm, it is +customary to perform the one-constant approximation for which K1 ≈ K2 ≈ K3 = K = +10−11 N. This assumption is fair for most ordinary nematics: for instance, in the case of +5CB at 298 K, one measures K1 = 6.2 pN, K2 = 6 pN and K3 = 8.2 pN [30, 31]. +The simplest class of linear defects consists in axial disclinations and they were firsly +9 + +considered by Oseen [32] and Frank [33] (for the class of perpendicular disclinations, proposed +by de Gennes, see for instance [34]). Orientation of the director field is ill-defined along a +line (say the z−axis) and n lies in a plane orthogonal to the defect axis (in our example, +the x − y plane). In cylindral coordinates, let ψ(r, θ) be the angle between the director field +and the radial unit vector. Then the Euler-Lagrange equations corresponding to a minimum +of fV simply writes as ∆ψ = 0. The solutions representing disclination lines are given by +ψ(θ) = mθ + ψ0, where m is the defect strength or topological charge (a priori in R) and ψ0 +a constant phase term. Around a closed loop, the total change in ψ is thus 2mπ. For the +director field to be well-valued, this variation is tied by the hodograph rule coming from the +Z2 symmetry of the nematic phase: +� +θ=2π +dψ = 2mπ = kπ +(2) +where k ∈ Z. Hence, the director field writes as +n = +� +� +� +� +� +cos(mθ + ψ0) +sin(mθ + ψ0) +0 +� +� +� +� +� , +(3) +with the topological charge constrained to be integer and half-integer, i.e. m = ±1/2, ±1, +±3/2,. . . +Disclinations with integer strengths are topologically removable and belong to the N = 0 +homotopy class: defects m = +1 and m = −1 are topologically equivalent and can be trans- +formed into one another by continuous deformations. They appear in optical microscopy +as thick lines and their core is not singular (possibility to escape into the third dimension). +Disclinations with half-integer strengths are not topologically removable and belong to the +N = 1 homotopy class. In this latter case, fibring over a circle about the defect line by +a line segment containing the director which is met at that point, gives a Mœbius ribbon +which twists along the loop an odd number of times [26] (on the contrary, for the N = 0 +disclination, one gets an ordinary ribbon with two sides). They appear in optical microscopy +as thin lines and they display a singular core structure. As the free energy density varies in +m2 and therefore, it is energetically more favorable for a wedge disclination to decay into two +Mœbius disclinations, as prescribed by the combination 0 = 1+1. It must be remarked that +besides |m|, other topological invariants (such as the self-linking number, Poincaré-Hopf’s +10 + +index...) are needed to characterize the topology of a linear defect, as a disclination can +globally self-connect, entangle with itself... +b. +The secrets of Fermat-Grandjean principle +In the geometrical optics limit, light +propagates along paths that can be traveled within the least time. In the case of isotropic +media, this variational formulation takes the form of the well-known Fermat’s principle, +established by Pierre de Fermat in 1662. In anisotropic uniaxial media, the constitutive re- +lations involve a dielectric tensor that displays two different principal permittivities, namely +ε⊥ and ε∥ (in a nematic, ε∥ corresponds to the permittivity in the direction of the director +field, whereas ε⊥ is the permittivity orthogonally to it). Fresnel’s equation then provides +two modes inside such material: the ordinary mode, behaving similarly as in an isotropic +medium with refractive index n2 = ε⊥, and the extraordinary mode which experiences a +direction-dependent refractive ray index given by [35]: +Ne(r) = +� +ε⊥ cos2 β(r) + ε∥ sin2 β(r) +(4) +where β is the angle between n and the local tangent vector T. In 1919, Grandjean extended +Fermat’s principle to uniaxial media and he showed that the energy carried by extraordinary +light rays propagates along paths obeying [8] +δ +�� +Ne(r)dℓ +� += 0 +(5) +where ℓ is the curvilinear abscissa that parameterizes a ray. +Because the director field changes from point to point, a nematic generally displays a +varying refractive index and hence, extraordinary light beams propagate into the medium +along curves (see Fig. 2). In the case of planar axial disclinations, the direction of n and +consequently β is known at each point. In that case, it can be shown that the integrand in +Fermat-Grandjean’s principle can be generally rewritten as [36, 37] +N 2 +e (r)dℓ2 = +� +ε⊥ cos2 [(m − 1)θ + ψ0] + ε∥ sin2 [(m − 1)θ + ψ0] +� +dr2 ++ +� +ε⊥ sin2 [(m − 1)θ + ψ0] + ε∥ cos2 [(m − 1)θ + ψ0] +� +r2dθ2 +− +� +ε∥ − ε⊥ +� +sin2 [2(m − 1)θ + 2ψ0] rdrdθ + dz2 +(6) +In a seminal work [38], Walter Gordon pointed out the formal analogy between light +propagation inside a moving dielectric and light propagation inside a non-Euclidean geome- +try. This idea was developed by many authors eversince [39–45], as it elegantly replaces the +11 + +FIG. 2. Light paths and director fields in the presence of a planar disclination (Up left: m = +1, ψ0 = π/2. +Down left: m = −1, ψ0 = π/2. +Up right: m = 1/2, ψ0 = π/4. +Down right: +m = −1/2, ψ0 = 0). Taken from [36]. +resolution of Fermat’s principle in a material medium by the search for the minimum-length +lines (or geodesics) of an empty curved space. The main asset of that point of view is that +one can use the toolbox of differential geometry to understand how the defect modifies trans- +port phenomena in its vicinity. To illustrate how this works, let us consider the example of +a (m = 1, ψ0 = π/2)-disclination (see Fig. 2). For this defect, Eq. (6) leads to the following +line element: +ds2 +3d = N 2 +e (r)dℓ2 = dr2 + α2r2dθ2 + dz2, +(7) +where α2 = ε∥/ε⊥. The line element is a fundamental quantity in differential geometry +and it simply consists in a generalization of Pythagoras’ theorem for computing distances in +arbitrary geometries. Here, instead of the familiar Euclidean line element ds2 +3d = dr2+r2dθ2+ +dz2, the term in α2 means that the circumference of a closed unit circle about the defect is no +longer 2π but 2πα instead: in other words, there is a mismatch angle (called Frank angle) +of value 2π(1 − α) compared to flat geometries. It is customary in differential geometry +12 + +to rewrite the line element as ds2 +3d = gijdxidxj, where Einstein’s summation convention on +repeated indices is used. g is called the metric tensor and it corresponds to a positive definite +quadratic form. The curvature scalar [46] as computed from the metric is: +R = 2π(1 − α) +αr +δ2 (r) +(8) +whereas the torsion tensor is identically zero. +An alternate approach to describe the influence of defects in optics, also from differential +geometry, consists in using the formalism introduced by Paul Finsler in his 1918 thesis, +for which there is no quadratic constraint on the geometry as in the Riemannian case [47]. +As a matter of fact, the arc length is given by a Finsler function F such that ds3d = +F (x, y, z, dx, dy, dz) instead of ds3d = +� +gijdxidxj. In the case of anisotropic media, F(r) = +Ne(r)dℓ and the metric corresponds to the Hessian of the ray index [48]. Ought to the +particularly simple dependency of the ray index with respect to coordinates, this formalism +turns out to be fully equivalent to Riemann’s approach (see discussion at the end of [36]). +A line element of exactly the same form as (7) appears in the geometric theory of defects +in elastic media [49], related to the strain field associated to wedge disclinations as will be +described in Section II D. Such line defects can be formed by either inserting or removing +a wedge of material of angle 2π(1 − α) with subsequent identification of the edges. In the +case of a removal wedge disclination of axis z (α < 1), the geometry surrounding the defect +is conical and can be easily pictured from the Volterra cut-and-weld process of Fig. 3. In +other words, a disclination can be pictured as a Riemann manifold, for which curvature is +only located on the disclination axis and vanishes everywhere else. +c. +Discussion +From the elasticity point of view (as opposed to optics) the description +of an axial wedge disclination by the geometry (7), or more generally by (6), calls for +several remarks (it is important to stress here that ε∥ and ε⊥ now are related to elastic, not +optical, anisotropy). First, a liquid crystal consists in an assembly of rod-like molecules and +modeling it as a continuous medium is not self-explanatory. Rigorously, the continuum limit +for nematoelasticity should come as a coarse grained approximation of molecular dynamics +and it should fail at the atomic scale. n(r) is defined statistically, as the average common +direction of the nematogens at each “point” in space. The “point” actually refers to a small +volume of space that includes enough molecules for the averaging process to be physically +significant. Hence, in practice, it means that the “point-volume” has to be large enough +13 + +FIG. 3. Volterra cut-and-weld process for a (wedge) disclination along z. +compared to the molecular scale a (typically a ≈ 20 Å) and that the variations of the +director field must occur at much larger scales than a. +Only then, the distorted liquid +crystal can be described as a continuous medium, as discussed by Oseen [32], Zöcher [50] +and Frank [33]. +A second caveat is related to the status of (7), which obviously possesses non-vanishing +curvature as in three-dimensional gravity. +Yet, the nematic actually lives in a three- +dimensional Euclidean space, which means that the background geometry is flat. How to +reconcile these two standpoints? Following the analysis from De Wit [51], the state described +by (7) does exist in the flat space, but only in an imaginary space where the medium is +relaxed: gij comes from the projection of this imaginary space onto the physical flat space, +in a similar way as a stereographic map projection transfers the geometric properties on +a 2-sphere (the Earth, with its meridians and parallels) onto a flat plane while deforming +them (Wulff net). It turns out that the geometric description of defects thus requires two +metrics: 1) The physical flat metric, δij, will be used to perform operations on tensors such +as raising/lowering indices... 2) The effective metric gij, which contains the elastic informa- +tion, will be used to determine the kinematics of low energy perturbations (geodesics, first +14 + +disclination axis +Frank angle +2=2元(1-α) +(α<1: removal)integrals...). +Third, one may naturally wonder what really happens on the defect axis and how to +refine our zero-width model. +In soft matter and more especially nematics, defect cores +are very narrow as well but they still belong to the realm of continuum mechanics. As +discussed in [8], a disclination line can accurately be described by a “two-phase model”: the +core consists in a tubular region, filled with the nematogens in isotropic phase (vanishing +order-parameter), and surrounded by the nematic phase (non-zero order parameter). This +approach is consistent with exact solutions obtained from the minimization of the Landau +– Ginzburg – de Gennes free energy. Yet, the last word has probably not been said about +disclination cores: observations made on lyotropic chromonic liquid crystals revealed that +the core region has several unexpected features (asymmetric non-circular interfaces between +the nematic and the isotropic phases, azimuthal and radial dependencies for the phase and +amplitude of the order parameter...) compared to classic two-phase models [52]. +D. +Analogue gravity: lessons and pitfalls +a. +Physics as geometry +The geometric description of transport near linear defects does +not restrict to optics near axial disclinations. Since the pioneering works by Bilby [53] and +Kröner [54] in the 1950s, this approach has been extended to elasticity theory as well [55, 56]. +In the noteworthy set of works [49, 57, 58], Katanaev proposed a general framework based +on Riemann-Cartan manifolds for dislocations and disclinations in elastic media but only +considered the strain tensor field as the relevant degree of freedom. An expression of the +effective metric gij in the medium rest frame can be obtained in the case of linear elasticity +as +gij = δij + 2εij +(9) +where εij denotes the strain tensor. Compared to ordinary elasticity theory (OET), the +geometric theory of defects is in principle more accurate (ordinary elasticity only reproduces +the first-order approximation of the geometric theory of defects [49]) and it is more versatile +(changing the kind of defect only requires changing the metric, instead of a complicated set +of boundary conditions in ordinary elasticity theory). Moreover, the geometric approach +is also likely to encompass many other kinds of linear defects of interest in liquid crystals +physics, such as screw dislocations in smectic A and C [59, 60] (in that case, the defect +15 + +must be described in terms of a Riemann-Cartan manifold, for which torsion is only located +on the dislocation axis and vanishes everywhere else [61]), dispirations in antiferroelectric +SmCA and the dimeric SmC2 [61, 62], edge dislocations in smectics [63, 64] (which are merely +disclination dipoles)... +The preceding examples testify that in many condensed matter systems, the effective +degrees of freedom are represented by specific field excitations that propagate over effective +Riemann-Cartan manifolds. Geometrization of physics is not a new idea. In Plato’s Timaeus, +an attempt was made to describe the world in terms of only five regular polyhedra and ever +since, geometrization of physics has been a dream pursued by many figures in science, +including René Descartes, Bernhard Riemann, William K. Clifford [65] (for an updated +account, see [66])... The most successful step forward in merging geometry and physics was +made in the twentieth century by Albert Einstein with the theory of general relativity: the +gravitational interaction turns out to be nothing more than a manifestation of the spacetime +curvature. The possible implications of that theory did not escape the attention of influencial +physicists such as Hermann Weyl [67], Arthur Stanley Eddington [68] and more especially +John A. Wheeler. In the seminal paper Classical physics as geometry [69], Wheeler and +Charles W. Misner borrow tools from cohomology, differential geometry, exterior algebra and +topology to fully merge gravitation, electrodynamics and geometry. Provided spacetime is +multiply-connected, Misner and Wheeler showed that similarly to mass, classical charge can +also be seen as a byproduct of the spacetime geometry. A particularly meaningful example +is the low-dimensional gravitational model proposed by Gerard ’t Hooft in the context of +quantum gravity [70] (see below III C): in 2+1 dimensions, ’t Hooft showed that gravitating +point particles can elegantly be described as conical point-like singularities of space-time, +each deficit angle being related to the particle’s total energy. Today, this kind of ideas has +spread out to the point where it has become an area of research on its own: analogue gravity +(for an extensive review, see [71] and more recently [72]). +b. +Pitfalls +Despite appealing to classical fields, analogue gravity is tricky and must be +handled with great care. Indeed, it relies simultaneously on two different manifolds: 1) the +background gravitational metric – which is experienced by all fields (generally Minskowski’s) +– is the outcome of Einstein-Cartan equations. It is a tensor, used for instance to raise and +lower indices of tensors, and as such, it is a covariant quantity, and 2) the effective metric – +which is experienced only by the fields coupled to matter – does not obey Einstein-Cartan +16 + +gravitational equations. +Its purpose is limited (for instance, to determine the geodesics +followed by the coupled-fields excitations, as it is not a covariant quantity. +Indeed, the +effective metric is derived from physical quantities which are defined in a privileged frame, +the medium rest-frame, and that are not invariant under Lorentz transformations. +As can be seen from (9), the effective metric superimposes the background Minkowski +metric and a correction taking into account the couplings between field and matter. In the +original experiment led by Hippolyte Fizeau, the changes in the velocity field of water (and +hence of the Gordon metric itself) were obviously ruled by the Navier-Stokes equations (for +the velocity field) instead of Einstein-Cartan equations. In other words, effective spacetimes +are generally stationary. Ref [73] pointed out that textures in nematic liquid crystals can +indeed be described by the space sector of an Einstein-like equation, with the elastic-stress +tensor replacing the energy-momentum tensor. The relevance of the effective metric is there- +fore restricted to calculations of properties related to the kinematic properties of the fields +coupled to matter. This encompasses as we said the geodesics of low-energy excitations +but also the less obvious cases of Unruh effect or Hawking radiation which are purely kine- +matic phenomena [74]. Therefore, the analogy between gravitation and condensed matter +is strictly kinematic but not dynamical. To rephrase Wheeler, analog spacetime tells matter +how to move... but matter does not tell analog spacetime how to curve. +What is the purpose of analogue gravity? In cosmology, putting a theory into test is +always a thorny challenge. In 1992, the great epistemologist Karl Popper already pointed +out that the “major theoretical problem in cosmology is how the theory of gravitation may be +further tested and how unified field theories may be further investigated” [75]. If the plentiful +harvest of low-energy observations (baryonic oscillation spectroscopy, gravitational wave in- +terferometry, mapping of the cosmic background ...) answered many questions, theoretical +models involving (trans)planckian scales bloomed even faster, for which experimental con- +firmations seem almost impossible – even in principle – to reach. A possible way out of this +conundrum is to take advantage of the richness and flexibility of condensed matter. Within +certain limits, analogues of gravity can be used to simulate different types of cosmological +objects (signature transitions events, cosmic strings...) and to investigate the transport of +bosonic and fermionic quasiparticles in nontrivial spacetimes. The next section reviews a +series of works dealing with non-standard cosmological models that can be investigated from +their liquid crystal counterparts. +17 + +III. +UNRAVELING THE UNIVERSE WITH LIQUID CRYSTALS: COSMOLOGY +IN THE LABORATORY +A. +Phase transitions in cosmology +a. +Thermal history of the universe +In many senses, cosmology consists in thermody- +namics applied to the largest expanding closed system: our universe. Our current under- +standing of cosmic history is indeed based on the Standard Hot Big Bang Model and it +originates in the pioneering works of three founding fathers: Albert Einstein, Alexander +Friedman and George Lemaître. In essence, this model states that about 13.8 billion-years +ago, the Universe was in an extremely hot dense state, consisting in a quark-gluon plasma, +and that it has expanded ever since. In the framework of grand unified theory (GUT), the +four fundamental interactions (the gravitational interaction, the electromagnetic interaction +and two lesser known forces, the weak nuclear interaction – responsible for radioactive β de- +cays – and the strong nuclear interaction – which ensures the cohesion of the atomic nuclei) +were then assumed to be unified at energy scales estimated at about 1016 GeV. +Each interaction is associated with internal (or gauge) symmetries: for instance, at today’s +energy scales, the electromagnetic force displays gauge invariance under the elements of U(1), +the unitary group of dimension 1 (for an accessible review on gauge theories see for instance +[76]). Above 1016 GeV, the group G containing the internal symmetries of grand unified +superforce is not known for sure and many candidates with exotic names are considered, +such SU(5), SU(6), SU(7), SU(8), SU(9), SO(10), SO(14), E6... [77] The universe expansion +played the role of a gigantic Joule-Thomson expansion, which caused a large temperature +drop driving cosmological phase transitions. For example, the last of these transitions is +the electroweak phase transition, occurring at energy scales about 102 GeV. It marks the +splitting of the electroweak force into an electromagnetic part, described by Maxwell’s theory +(1865), and the weak nuclear part, the first theory of which being Fermi’s theory (1933). +This transition involves a spontaneous gauge symmetry breaking: the high temperature +gauge symmetry group SU(3)c × SU(2)L × U(1)Y broke into SU(3)c × U(1)em [77]. +Let us now examine the topology of vacuum manifold (that is the set of field configurations +minimizing the free energy modulo gauge transformations), which is the equivalent of the +order parameter space M in condensed matter physics. In [78], Jeannerot et al determined +18 + +the homotopy content corresponding to all eligible groups G likely to decay below 1016GeV +into SU(3)c × SU(2)L × U(1)Y . Their conclusion leaves no doubt concerning the formation +of cosmic strings: +. ..among the SSB schemes which are compatible with high energy physics +and cosmology, we did not find any without strings after inflation. +(if one assumes that the universe is topologically multi-connected, cosmic strings and +monopoles may appear – not single but pairwise –, whereas two-dimensional defects – +domain walls – cannot form at all [79]). +b. +Kibble-Zurek mechanism +Cosmic inflation is a period of extremely fast expansion +of the Universe scale factor (typically a factor 1026 within 10−32 seconds) that presumably +happened at the very beginning of the universe [80]. From the point of view of statistical +physics, inflation is nothing more than a quench and as such, it is likely to favor the formation +of topological defects. In 1976 [81], Tom Kibble introduced a three-step mechanism (later +refined by Zurek [82] who included the sensitivity to the quench speed) to describe the details +of this quench. +Basically, the Kibble-Zurek mechanism (KZM) consists in a nucleation +process very similar to what happens at the isotropic-nematic phase transition, but instead +of having an order locally described by the director field n, it is here described by the phase +of a complex scalar field generically called a Higgs field – or an inflaton, because it needs +not be the Higgs field responsible for the later breaking of electroweak symmetry. First, +ordered protodomains (analog to the nematic spherulites) with no correlation between each +other are formed and at the scale of a whole protodomain, the fast temperature drop due +to inflation causes the Higgs field to locally take a non-vanishing vacuum expectation value +and hence to make a phase choice. Then the protodomains grow in size until they coalesce. +But as they were not correlated, the choices for the Higgs phase (technically, its vacuum +expectation value) do not match in general, and line singularities of the Higgs appear when +the boundaries of protodomains finally meet. These linear singularities are called cosmic +strings. +Besides this qualitative predictions, the KZM also makes quantitative predictions such +as the scaling dynamics of the cosmic string network, the average density of defects, cor- +relations between defects and antidefects... In the 1990s, several works [27, 83–87] showed +that the KZM, originally developped for cosmology, was also perfectly describing line defects +19 + +in nematics with the very same scaling coefficients. For instance, this model predicts that +in 2D the density of strings scales as ρ ∼ (t/τq)α with a critical exponent αth = 0.5, and +measurements done by [27] with 5CB indeed gave αth = 0.51 ± 0.04. To sum up: defects +consist in regions that cannot relax into the new vacuum or equivalently that are unable to +make the transition into the new ordered phase, and they occur during phase transitions +in cosmology and in liquid crystal physics that seem to belong to the same universality +class. But the family resemblance goes further. Networks of cosmic strings and networks of +disclinations also share similar intersection processes: 1) when two line defects intertwine, +they may reconnect the other way as they cross (intercommutation) [27, 88] and 2) when +one line defect self-intersects, it creates a loop [89, 90]. +c. +An almost perfect analogy? +Last but not least of these common points: the geometry. +Nambu-Goto strings, which are the simplest cosmic defects one may expect in cosmology, +consist in linear concentrations of energy and as such, they are considered as infinitely +thin objects (as the thickness of a cosmic string is estimated at 10−28 cm, this is a fair +approximation[91]). As required by thermal field theory and general relativity, the geometry +around a Nambu-Goto string is described by the Vilenkin’s line element [88]: +ds2 = −dt2 + dr2 + (1 − 4Gµ)2 r2dθ2 + dz2 +(10) +where µ is the string energy density estimated at about 10 million billion tons per meter +(we adopt hereafter the customary unit system of cosmology where c = 1). The space part +of this element is identical to (7): it is a conical geometry corresponding to a removed Frank +angle [92] (typically, for a GUT scale string, this angle is a few seconds of arc). The reader +interested in the classical gauge theory of string interactions in curved spacetimes can refer +to Ref.[93]. From the standpoint of the soft-matter physicist, Nambu-Goto strings can be +understood as the cosmic counterparts of wedge disclinations. How to make sense of such +incredible similarity? For the most part, this question is still open, but a noticeable attempt +to address it was done in [73]: in essence, the reason is that equations of nematoelasticity +have the form as the spatial sector of Einstein’s field equations, with the elastic-stress tensor +playing the role of the energy momentum tensor. +As the analogy between gravity and nematoelasticity does not concern time components, +one expects that the dynamics of a cosmic defect cannot be directly mapped with those +of a disclination. There are other discrepancies between cosmic and elastic defects that +20 + +one must bear in mind to avoid fallacies. Obviously, the motion of disclinations is classical +(typically a few µm per second) whereas cosmic strings are ultra-relativistic. Dissipation +mechanisms for cosmic strings are due to radiation of gravitational waves, while those in +liquid crystals are friction-dominated. What is the outcome on the dynamics of the defects? +In cosmology, monopoles annihilate in pairs (Langacker-Pi mechanism), but they do not +annihilate fast and early enough to avoid that the Universe becomes monopole dominated +(which is why inflation is necessary, as it drives monopoles very far away from each other). +On the contrary, elastic hedgehogs in a nematic annihilate rapidly according to a scaling +law. At a more fundamental level, this is linked to the fact that in high energy physics, +broken symmetries are gauged (or internal) whereas in liquid crystals, broken symmetries +are geometrical: in the first case, one is dealing with “gauged defects” and in the second +case, one is dealing with “global defects”. +B. +Beyond cosmic wedge disclinations +a. +The way out of an observational dead-end +Cosmic wedge disclinations exist either as +stable infinite straight lines (their equation of state simply equates the string energy density +to its tension µ = T) or as closed loops that radiate away gravitational waves until they +vanish. When moving, strings happen to distort spacetime such that at all scales, matter +accretes along its wake into sheet-like structures. +They may account for the formation +of large-scale structures in our universe (including the Great Wall) and they have several +expected observable signatures such as the Kaiser-Stebbins effect [94, 95] (an asymmetric +Doppler shift giving rise to anisotropies of the cosmic microwave background), gravitational +lensing [96] (not in the form of an Einstein ring, but as a double image instead), geometric +phase (Aharonov-Bohm effect but with a cosmic string replacing the flux tube [97])... Up to +now, data collected by the PLANCK mission (2014) only settle upper bounds on the string +parameter µ [98] and in 2020, observations of the stochastic gravitational wave background +(NANOGrav experiment) may have provided with first evidences for cosmic strings [99–101]. +The non-conclusive observations of Nambu-Goto strings call for the search of refined mod- +els for linear defects. In fact, the zero-width approximation and the straightness of cosmic +strings are probably too coarse to account for realistic defects. Hiscock [102] and indepen- +dently Gott [103] suggest to smoothen this singularity by introducing two string models with +21 + +a core structure of constant curvature: the flower-pot model (with zero curvature) and the +ballpoint-pen model (with non-vanishing curvature). In the Gott-Hiscock thick cosmic string +spacetime, the metric tensor is piecewise-defined and it must obey matchings conditions at +the core radius [104]: the extrinsic curvature of the boundary should be the same whether +measured in the interior or exterior region (O’Brien-Synge-Lichnerowicz jump condition). +In contrast, thanks to experiments [52, 105] and molecular simulations [106, 107], much is +known about the NLC disclination core. In particular, there is strong evidence for biaxiality +and that strength +1 disclinations are in fact bound pairs of strength +1/2 ones, which +may be manipulated by electrical fields [108]. We note that this rich structure may serve +as an inspiration for novel cosmic string core models. In the same line, instead of being +perfectly straight, linear defects can present cusps, kinks and wiggles: the averaged effect +of these perturbations increases the linear mass density µ and decreases the string tension +T, as prescribed by the equation of state µ T = µ2 +0 [109–111]. Compared to straight string, +the geometry remains conical but the deficit angle is larger than in the straight string case, +which increases polarization anisotropies of the cosmic background radiation [112]. +There are many other ways to dress a Nambu-Goto string such that it may account +for observational results [113]. From an extension of Volterra process to 3+1 dimensions, +Puntingam and Soleng showed that there was only 10 ways to modify a Minkowski spacetime +into different pseudo-Riemann–Cartan geometries with respect to the Poincaré group. For +example, a cosmic linear defect can display chirality [114–119]: in that case, the defect +carries torsion along its axis and one gets the cosmic counterpart of a screw dislocation in +a smectic liquid crystal. Twisted Nambu-Goto strings (or cosmic dispirations), consisting +in spacetimes with delta function-valued curvature and torsion distributions have also been +considered, as they combine both rotational and translational anholonomy [120–123]: as +mentioned earlier, their effects on light could be tested from experiments done with elastic +dispirations SmCA and SmC2. +b. +Going further +Rotating disclinations are not likely to be stable but it is worth +mentioning here that their cosmic counterparts have been long predicted in the literature +[124]. A metamaterial analogue of the rotating cosmic string spacetime has been proposed +[125], as well as a superfluid vortex analogy [126]. One of the most interesting properties of +the spinning string is its association to closed timelike curves which may find applications +in time travel [127]. Incidentally, parallel cosmic strings moving in opposite directions have +22 + +been suggested [128] as a prototype time machine. Related to, but not really a model for +spinning strings, is the case of a hyperbolic nematic-based metamaterial with a disclination +which was addressed in [129]. Along the same line, in [130] it was proposed a disclination +model for the compactified Milne model of a cyclic universe. More details on this model in +Section III C. +Among the gauge strings, a very interesting possibility is the semilocal string [131]. Like +Dirac’s string of magnetic dipoles, semilocal strings end on gauge monopoles. They are +analogous to real disclinations in liquid crystals which, due to the finite size of a liquid +crystalline sample, must end somewhere (hedgehog, 2D disclination on the liquid surface or +on receptacle wall) or else, form a loop. Apropos, disclination loops in active nematics have +very complex dynamics (including chaos) and may present recombination episodes [90]. +Defects in liquid crystals have inspired many other proposals in cosmology. GUT allows +for discrete gauge symmetry groups, the standard Z2 parity and one Z3 parity, which are the +only anomaly free groups that remain unbroken at low energy [96, 132]. The corresponding +cosmic strings are generically called Zn-cosmic strings. +Based on the known physics of +Moebius disclinations, which are commonly observed in nematics, Satiro and Moraes have +investigated some cosmological outcomes of Z2 cosmic strings [133]: in particular, they +showed that Z2-cosmic strings display both positive and negative mass density regions. +Bearing in mind the back and forth interplay between cosmology and soft matter, one +cannot avoid to mention the latest works of Maurice Kleman, who imported homotopy +theory from condensed matter to astrophysics and cosmology [134–136]. In particular, he +conjectured and classified new families of cosmic defects (such as r-cosmic forms) allowed in +a four-dimensional maximally symmetric spacetime [136]. +C. +Black holes and Early universe +a. +Black holes, white holes, wormholes +This is sometimes referred to as the “cosmology +in the laboratory” game plan and it covers topics such as classical black holes [137]-[138], +Hawking radiation [139]-[140], wormholes [141]-[142]... For instance, in Haller’s approxima- +tion, the hydrodynamics of a nematic liquid crystal radially flowing down a drainhole is +23 + +experienced by light beams as the equatorial section of the Schwarzschild’s metric +ds2 = − +� +1 − 2M +r +� +dt2 + +dr2 +� +1 − 2M +r +� + r2(dθ2 + sin2 θdφ2) +(11) +for a specific velocity profile. The ordinary and extraordinary indexes of the NLC depend on +the scalar order parameter of the liquid crystal. So, it was possible to taylor those indexes +to get the proper optical metric. In order to achieve this, the Beris-Edwards hydrodynamic +theory wass used to connect the order parameter with the velocity of the liquid crystal flow +at each point. This was done in Ref. [143]. +More recently, an optical analogue of a wormhole threaded by a cosmic string was de- +scribed in [142]. +Wormholes are solutions of Einstein’s equations that connect different +regions of the spacetime. For instance, a spherically symmetric wormhole can be obtained +by joining two Schwartzschild black hole spacetimes by a spherical hole carved around each +singularity. +Wormholes are usually represented by “embedding diagrams”, which are 2D +slices of the 4D structure immersed in Euclidean 3D space. The embedding diagram of the +notorious Morris-Thorne [144] wormhole is obtained by taking a t = const., θ = π/2 section +of the spherically symmetric spacetime described by the metric +ds2 = −c2dt2 + +dr2 +1 − b2 +0/r2 + r2(dθ2 + sin2 θdφ2). +(12) +The restricted metric, ds2 = +dr2 +1−b2 +0/r2 +r2dφ2, can be embedded in a 3D Euclidean space with +metric ds2 = dz2 + dr2 + r2dφ2 such that z = z(r) is the equation of the embedded surface +of revolution. For metric (12) the result is the catenoid. +A thin nematic film on a catenoid with director field aligned either circularly or radially +(see Fig. 4) has an optical metric given by [142] +ds2 = dτ 2 + α2(τ 2 + b2 +0)dφ2, +(13) +where α = no/ne for the circular case, and α = ne/no for the radial one. The coordinate τ is +the arc length of the catenary that under rotation gives rise to the surface. The parameter +b0 is the radius of the wormhole “throat”. For α = 1, Eq. (13) reduces to the catenoid +metric. It is clear from Eq. (13) that, asymptotically (τ >> b0), the optical metric of the +disclination is recovered. This is also evident from the top view of the catenoids of Fig. 4. +This optical model simulates the conical spacetime of a Morris-Thorne wormhole threaded +by a cosmic string. The geodesics as obtained in [142] are represented in Fig. 5. +24 + +FIG. 4. Director field for circular and radial +1 disclinations on the catenoid, respectively. Taken +from [142]. +(a) +(b) +(c) +FIG. 5. +Assorted geodesics for the circularly decorated catenoid. +The blue lines represent the +isotropic case α = 1. The red and black lines represent, respectively, circular (deficit angle) and +radial (surplus angle) disclinations with α = 0.85 for (a) and (b), and with α = 0.98 for (c). Taken +from [142]. +From Fig. 5 it is clear that the two parts of the wormhole joined by its throat act as a +black hole/white hole pair. +b. +Road to quantum gravity +A major contemporary challenge in physics is to find an +extension of General Relativity able to describe gravity at all energy scales, in particular at +the very beginning of the universe. This is the mission devoted to quantum gravity theories, +which have the daunting task of reconciling Einstein’s general relativity and quantum field +theory. Despite promising attempts including superstring theories, M-theory or quantum +loop gravity, no proposal is entirely satisfactory up to now, and even so, the energy scales +required to test these theories are far beyond our current scientific capabilities. A way out +of this gridlock is to rely on simpler models that capture the essential features of quantum +gravity but remain connected to low-energy-physics systems, i.e. analogue gravity. The +rare pearl was first introduced in a seminal paper by Deser, Jackiw and ’t Hooft [145]: 2+1 +25 + +gravity with point-particle sources. +The main point is that there is no gravitational degrees of freedom in three dimensions +[146], which drastically simplifies general relativity (now an exactly solvable model [147]). +Within this framework, the geometry surrounding a point-particle is a conical singularity, +the mismatch angle being proportional to the particle’s mass. In other words, conical de- +fects represent point particles coupled to gravity in 2+1 spacetimes. After Katanaev [57] +first pointed out that the theory of linear disclinations was isomorphic to the 2+1-gravity, +Kholodenko [148] used the apparatus of quadratic differentials to establish the connection +between Deser, Jackiw and ’t Hooft model and defects in liquid crystals. In essence, the exis- +tence of massive particles considered as field singularities is directly related to the topology of +the underlying manifold (the Euler characteristic) and to the emergence of the induced sad- +dles: this means that 2+1 Einstein’s equations are strictly equivalent to the Poincaré-Hopf +theorem (see section 5.2 in [148]), the Hopf quantization rule making the direct connection +between particles masses Mi and the defect topological charge m, 4GMi = m [149]. +The 2+1 gravity model can therefore be experimentally investigated from a network of +parallel disclinations lines in a 3D nematic sample. Geometry of disclinations networks has +been theoretically investigated in the literature, sometimes allowing for analytical expres- +sions for the metric tensor [150–152]. Several authors have shown the possibility to design +arrays of topological linear defects from photopatterning techniques [153–157] and even to +manipulate them [158, 159]. If this last point opens the possibility to emulate collisions be- +tween particles in the 2+1 model, it is even more interesting for the extension of the Deser, +Jackiw and ’t Hooft model to 3+1 dimensions [70]: matter particles are represented by a +gas of piecewise straight string segments that are likely to collide with a higher frequency. +The strings display both positive and negative mass densities, i.e. they are associated to +α < 1 and α > 1 Frank angles, which makes liquid-crystal-based experiments particularly +promising to investigate such models. This model may also have deep connections with +Regge calculus in quantum gravity, where the smooth curved spacetime is replaced by a +piecewise-flat simplicial manifold. This is like the triangulation of a surface in 3D where the +local curvature is described by the dihedral angle between adjacent triangles (the triangle is +a 2D simplex). The effect of gluing the edges of the simplexes generate a network of cone-like +singularities (Regge cones) which are analogs to wedge disclinations [160, 161] (see Fig. 6). +26 + +FIG. 6. Triangulation of a sphere at the Itapetinga radiotelescope (Brazil). Covering a curved +surface by the triangles generates dihedral angles all around the sphere. +c. +Non-standard cosmology +Cosmology at transplanckian scales is a thorny problem, +both theoretically and of course observationally. For instance has the universe popped up +from a unique singular event, the Big-Bang? And if so, how not to wonder what could have +happened before it and how to design experiments to test these theories? Today, many +high-energy physics theories such as quantum loop gravity and supertring theories entice +the search for cyclic universe models, that is an endless repetition of big crunches followed +by big bounces, along the same line of thought as the Stoics’ concept of palingenesia. A +safe transition has been proposed [162, 163], where the singularity is nothing more than the +temporary collapse of a fifth dimension, the three space dimensions remain large and time +keeps flowing smoothly. A toy model for the geometry of this transition is the compactified +2D Milne universe MC [164, 165]. The Milne universe metric is given by +ds2 = −dt2 + t2dχ2 + t2 sinh2 χ +� +dθ2 + sin2 θdφ2� +(14) +and it was proposed by E.A. Milne in 1933. It represents a homogeneous, isotropic and +expanding model for the universe with a negative curvature. In order to compactify the +27 + +Milne universe on hypersurfaces of fixed solid angle, let the variable χ acquire some period +denoted as 2πκ: here, 0 < κ ∈ R1 is a constant parameter for compactifications. After +reparametrization, the line element corresponding to the compactified Milne universe finally +writes as +ds2 = −dt2 + κ2t2dφ2 +(15) +where t ∈ R1. As can be seen from the disclination line element (7), the presence of κ2 in +the above metric indicates a conical singularity of the curvature at the origin (see Fig. 7). +The passage through the initial singularity has several unusual features [130, 166]: the +singularity acts as a filter for classical particles and a phase-eraser for quantum ones. The +timelike geodesics of (15) reveal that depending on their angular momentum J, particles have +two ways of crossing the singularity: 1) For non-vanishing J, a two-step dynamics consisting +in an inward stable motion before the singularity, followed by outward stable motion on the +other side, with a memory loss of the particle kinematical properties (quantum mechanically, +this effect simply comes from strong oscillations of the phase of the wave function at the +singularity. 2) For J = 0, a one-step dynamics consisting in a straight line through the +collapse: yet such trajectories are very unstable since small perturbations in the value of J +causes large deviations on the trajectories. +Probing how particles behave in MC can be tested in the laboratory from hyperbolic +liquid crystal metamaterials (HLCM): this means that the permittivity along the director +axis ε∥ < 0 and the permittivity perpendicular to the director axis ε⊥ > 0 are of opposite +sign [167]. Such media can be made from a host nematic liquid crystal that includes an +admixture of metallic nanorods [168] or coated core-shell nanospheres [169]. To retrieve the +Kleinian double-cone geometry, the HCLM must be endowed with an hyperbolic disclination: +the line element writes as ds2 = ε⊥dρ2 − ε∥ρ2dφ2 + ε⊥dz2, which after a rescaling becomes +ds2 = −γ2r2φ2 + dr2 + dz2. This line element is relevant only by the extraordinary modes +and for radial injection conditions (planar trajectories z = Cst), the geometry experienced +by extraordinary rays is perfectly identical to that of the compactified Milne universe. +A stable configuration for the director field may be obtained from a cylindrical shell +of HLCM with homeotropic anchoring at the boundaries. In the geometrical optics limit, +extraordinary light paths turn out to be Poinsot’s spirals as for the compactified Milne +universe. The practical realization sets limits to the efficiency of such analog device for +the classical particles. First, the analysis holds only within a limited frequency bandwidth +28 + +FIG. 7. Timelike geodesics with the radial time t given in units of t0 and κ = 1/3. The blue and +green (orange and red) lines are moving away (towards) from (to) the singularity. Furthermore, +particles following the trajectories in the first (third) and second (fourth) quadrants are spinning +clockwise (counterclockwise). The blank point at the origin is just to emphasize that the curves do +not reach the singularity. Taken from [130]. +due to the resonant nature of the used core-shell spheres. Second, as previous phenomena +concern the extraordinary mode, an efficient optical absorber should include a filter to shut +off the ordinary wave. Finally, it should be noticed that the present model concerns optics +inside a bulk hyperbolic material: to design a perfect optical analog, the hyperbolic medium +must be impedance matched to avoid sizable reflections at the interfaces. The analogy was +also extended to quantum particles by investigating light in the scalar wave approximation +in the same device. +29 + +t +3 +f+, J <0 +f+, J > 0. +f-, J >0. +J0 +3 +J=0FIG. 8. Geodesics of the channel of defects in the potential landscape. Taken from [129]. +IV. +TAYLORING TRANSPORT WITH LIQUID CRYSTALS: DEFECT-ENGINEERED +MATERIALS +A. +Acoustics +a. +Ballistic guiding +The geometric description of linear defects revealed wedge discli- +nations carry curvature along their axis: a positive Frank angle corresponds to a conical +geometry that focuses incoming light rays, in similar fashion to what happens with a con- +verging lens. Conversely, a negative Frank angle corresponds to a saddle-like geometry that +scatters geodesics, in the same fashion as a diverging lens. It is worth noticing that the effect +of a disclination does not limit to the eikonal approximation, as it also diffracts incoming +waves: from the present geometric approach, computing the differential scattering cross sec- +tion of a wedge disclination showed good agreements with theoretical results obtained by +Grandjean from standard acoustics [170, 171]. +The effect of a single wedge disclination on rays being clarified, one can legitimately won- +der if a well-suited arrangement of such defects can be used to taylor the propagation of +sound (we recall that photopatterning techniques now allow for the practical realization of +almost any kind of arrays). In [151], a channel of disclination dipoles was considered, con- +30 + +V(x,y) +10sisting in two infinite rows made of alternate disclinations separated by distance 2a (a kind +of von Kármán alley), the distance between the rows being 2b. The positive disclinations +are at points located at (na, (−1)nb), n ∈ Z, while negative disclinations have coordinates +(na, (−1)(n+1)b), n ∈ Z. As always done in geometric models, the bulk medium is consid- +ered in the continuum limit (i.e. limit of a vanishing lattice spacing). The corresponding +background geometry writes as +ds2 = −c2dt2 + e−4V (x,y) � +dx2 + dy2� ++ dz2 = gµνdxµdxν +(16) +where c is the local speed of wave packet and V is the acoustic potential given by [151]: +V (x, y) = +|F| +4π ln +�� +cosh2 � π +2a(y − b) +� +− cos2 � πx +2a +� +cosh2 � π +2a(y − b) +� +− sin2 � πx +2a +� +� � +cosh2 � π +2a(y + b) +� +− sin2 � πx +2a +� +cosh2 � π +2a(y + b) +� +− cos2 � πx +2a +� +�� +(17) +where |F| is the absolute value of the Frank angle that characterizes the ±F defects. The +sound paths are attracted by the positive defects while repelled by the negative ones (see +Fig. 8 and 9). Adjusting the defect strengths along with parameters governing the geometry +of a cell (namely a,b) opens the possibility to taylor material properties of the sheets, but +this will only be achieved numerically considering the complexity of analytical expressions. +Sound paths are yet very sensitive to the shooting angle. Hence, a thorough optimization of +the distribution of defects deserves an additional treatment of chaos involving the statistical +tools of dynamic hamiltonian systems. +b. +Acoustic rectification +Differential geometry models for acoustics originates from +[172] where vorticity effects in isotropic fluids were investigated. In nematics, for a pla- +nar horizontal configuration, the acoustic metric experienced by the extraordinary mode is +formally identical to (6) with the substitutions ε⊥ ↔ ρv2/C33 and ε∥ ↔ ρv2/C11, where ρ +is the mass density, v is the velocity of sound in the isotropic phase, C33 and C11 are elas- +tic constants respectively along the director’s direction and in directions orthogonal to it. +When the nematic medium is confined inside a capillary tube (radius R) with homeotropic +boundary conditions, the director field tends to be radially oriented everywhere but on the +central axis where an orientational singularity lies, but to reduce the elastic energy of this +configuration, the director escapes in the third dimension [63, 173] and the nematic relaxes +31 + +FIG. 9. Different geodesics, shot from the origin, in the channel of disclinations geometry. The +positive disclinations correspond to red contours while negative disclinations correspond to blue +contours. Depending on the shooting angle, the propagation of phonons may be guided by the +street of topological defects. Taken from [129]. +into a funnel-shaped configuration, known as the escaped radial disclination (ERD) where +the delta-distributed Ricci scalar becomes an extended smooth one [174]. +In general, rectification effects come from an asymmetry of the system in the direction +along which the transport phenomenon occurs. Usually, this is generally achieved by relying +on gradients of physical properties (e.g. pore density [175], distribution of compositional +defects [176]...), asymmetric geometries [177, 178]... all examples of situations implying hard +and non-flexible systems. Liquid crystals naturally provide a stable but flexible configuration +corresponding to such asymmetry, the ERD. In the spirit of a low-cost soft-matter-based +solution, satisfying levels of acoustic rectification have been obtained by combining the +asymmetry of the ERD configuration to that of a container consisting in conical frustum +of varying radius R(z) [179]. The inner surface prepared to produce the desired anchoring +angle[180]. The anchoring angle adapted to maintain the ERD configuration. α depends on +the surface geometry (radius), on the liquid crystal nature (elastic constant K, saddle-play +32 + +0.5 +0.5 constant K24) and on the surface treatment. Reference [179] considered acoustic waves in a +frequency range between 20 Hz and 20 kHz (the average human audible range) propagating +in 5CB for the ERD configuration. The rectification parameter used to estimate the acoustic +device’s efficiency is the percent standard deviation of the lowest variation on the acoustic +intensity +Acoustic rectification(%) = +���� +∆Ibt − ∆Itb +min (∆Ibt, ∆Itb) +���� × 100 +(18) +where ∆Ibt = It − Ib is the acoustic intensity variation if the wave comes from the bot- +tom to the top of the conical frustum and ∆Itb = Ib − It is the analogous variation for the +counterpropagating case. Numerical simulations show a rectification effect for a longitudinal +plane wave propagating along the conical frustum axis (see Figure 10). The optimization +of the device parameters (geometry of the conical frustum, anchoring conditions the rectifi- +cation effects...) allows to reach rectification levels up to 1300% for a continuous frequency +bandwidth [181]. +FIG. 10. Left: Conical frustum with an ERD. Middle: Pressure field for the incoming waves from +bottom to top. Right:Pressure field for the incoming waves from top to bottom. Taken from [181]. +33 + +mPa +mPa +7.47237 +0.58721 +7.47236 +0.5872 +7.47235 +7.47234 +0.58719 +a) +20 +Jm +b) +20 +Ars +7.47233 +0.58718 +50 +50 +7.47232 +50 +50 +0.58717 +s) <0 +0 +μm +-50-50 +m +0 +- +Aim +7.47231 +-50-50 +μm +0.58716 +7.4723 +0.58715B. +Optics +a. +Waveguiding and light concentration +Manipulation of light has become a major issue +in a large number of applications ranging from solar energy harvesting to optical sensing. +The beam steering technique relies on a modulation of refractive indices to guide light +in a given direction ([182–185]). More recently, the possibility to continuously deflect in +arbitrary directions and/or to simultaneously focus/defocus an incoming light beam has +been demonstrated from multiple stacked nematic liquid crystal cells—building blocks [186]. +Another possibility to guide light beams is to use optical waveguides with nematic cores +in radial escaped disclination configurations: the defocusing due to natural diffraction is +compensated by the converging lens effect resulting form negative birefringence [187–191]. +Light focusing has long been suspected of suffering severe limitations, the Rayleigh crite- +rion forbidding beam sizes below half of a wavelength. Recently, the advent of metamaterials +provides new hopes for overcoming the diffraction limit using superlenses [192]. Another +promising possibility is to use an hyperbolic liquid crystal metamaterial (HLCM), obtained +from an admixture of metallic nanoobjects to nematics [193]. As seen in the previous sec- +tion, the permittivity along the director axis ε∥ and the permittivity perpendicular to the +director axis ε⊥ have opposite signs. For an orthoradial director field, the effective metric +writes as gij = diag (1, −α2ρ2, 1) and in the eikonal approximation, the light paths are the +aforementioned Poinsot spirals: the hyperbolic defect behaves as a sink for light paths [194]. +The smaller the value of α, the stronger is the spiraling behavior, 1/α corresponding to the +defect vorticity. Concentration of light by an hyperbolic disclination extends beyond the +geometrical optics limit. In the scalar wave approximation, the complex amplitude Φ of the +wave is governed by the generalized form of the d’Alembert equation, involving the Laplace- +Beltrami operator instead of the ordinary Laplace operator. The wave equation writes as +a modified Bessel differential equation of imaginary order iℓ/α and the solutions are linear +combinations of the modified Bessel functions of first and second kind, respectively. The +intensity distribution for the propagating fields shows 1) that the electromagnetic field con- +centrates along the axis of the device, and 2) that the bigger the value of the frequency, the +smaller the light rings are (see Fig. 11). +34 + +FIG. 11. Examples of intensity profiles, representing the transverse field distributions concentrated +in the vicinity of the hyperbolic defect. Taken from [194]. +b. +Optical vorticity +Active beam shaping has also emerged as a major trend in modern +optics. The idea is to taylor the amplitude, the phase or the polarization of an optical +wavefront from real-time driven systems that ideally must be compact enough, highly-flexible +but yet have low manufacturing costs. Ought to their high response functions, liquid crystal- +based devices naturally fulfill all these requirements and have emerged as promising low- +cost and easy-to-manufacture alternatives to MEMS, moving opto-mechanical devices and +photonic crystals [195, 196]. +In nematics, the orbital angular momentum carried by light beams can be tuned from +q-plates. A q-plate consists in an inhomogeneous liquid crystal cell endowed with a discli- +nation of topological charge q (for details regarding the dielectric tensor, see [197]). When +an electromagnetic wave propagates inside the medium, its components acquire designed +phase shifts (Pancharatnam-Berry phase) that trigger spin-to-angular momentum conver- +sions. This results in light beams displaying optical vorticity, i.e. the wavefronts are helical +and the intensities profiles distribute in doghnut-like shapes [198–203]. [204] demonstrated +from FDTD simulations that disclination lines can transform the state of polarization of +beams propagating along their axis. Umbilics ending disclination lines are also identified as +35 + +structures generating optical vortex arrays at predetermined wavelength [205]. +Nematics are not the only contenders in the contest for optical vorticity. In Ref. [206] +the Raman-Nath diffraction was used to generate optical vortices from edge dislocations in +the stripe pattern of a cholesteric liquid crystal (cholesterics are chiral nematics for which +the director whirls around a well-defined direction). Cholesterics were also considered in +[207], where it has been theoretically and experimentally demonstrated that optical vortices +were generated from a Bragg-reflection-based device, therefore likely to operate at multiple +wavelengths. Recently, charged particles crossing a cholesteric plate were reported to radiate +purely twisted photons [208]. Chiral nematics are also likely to generate defect textures of +a more complex kind than that optical dislocations [209]. Beside cholesterics, smectics also +showed their potentialities for optical vorticity. [210] produced an optical vortex from focal +conic domains, whereas in [166], screw dislocations in smectics were shown to imprint their +torsion onto wavefronts (see also [211, 212] for a solid-state-oriented context). +C. +Heat transfer +a. +Principles of thermal design +Manipulation of heat flux raises intensive research ef- +forts because of the abundant wealth of potential applications including thermal shielding or +stealth of objects, concentrated photovoltaics or thermal information processing (heat-flux +modulators, thermal diodes, thermal transistors and thermal memories). These prospects +come from the possibility of designing energy paths in a fashion similar to that of light in +transformation optics. To do so, the first step is to understand the main peculiarities of +heat transfer in the presence of a non-Euclidean geometry. Generally speaking, diffusion of +a passive scalar (for instance the temperature field) can be seen as a collection of Markov +processes obeying the stochastic Fokker-Planck equation. In the case of Brownian motion, +the Fokker-Planck equation reduces to the well-known parabolic heat equation [213]. When +considering diffusion processes in the presence of a non-Euclidean space, the problem is ad- +dressed, as already discussed, by replacing the Laplace operator with the Laplace-Betrami +operator ∆LB [214]: +∂T +∂t = D∆LBT. +(19) +Here, D is the diffusivity and its value depends on the material properties. Ought to the +form of the metric of a wedge disclination, heat conduction locally occurs as in a monoclinic- +36 + +like crystal with no internal source [215]: the heat flux vectors are no longer perpendicular +to the isothermal surfaces, which are bent depending on the value of the Frank angle. In +other words, disclinations in nematics generate thermal lensing effects. +FIG. 12. Top: Temperature field (a) and heat flux field (b) for a radial director field (homeotropic +anchoring) and α = +� +C33/C11 = 0.5 Bottom: Temperature field (a) and heat flux field (b) for an +orthoradial director field (parallel anchoring) such that α = +� +C11/C33 = 2. Taken from [216] +Once the basic effects of single line defects are understood, the next step is to taylor them +to guide heat. To do so, let us consider a hollow cylinder, inside which there is the core region +where one aims at controlling the conductive heat flux. The cylinder is inserted inside a +conducting solid sandwiched between two heated vertical plates. The host material consists +37 + +(a) +(b) +(a) +(b)of a homogenous isotropic medium, whereas the intermediate thick cylinder consists of a +nematic liquid crystal in a disclination-like configuration (no disclination core). For thermal +management, mesophases with low melting and high clearing temperatures are required: a +range of about 100 K can be reached by using eutectic liquid crystal mixtures (or “guest- +host systems”). Numerical simulations [216] confirm the possibility of a strong heat guiding +phenomenon: depending on the value of elastic constants C33 (along the director) and C11 +(along any direction perpendicular to the director), the device can either cloak the core region +from the heat flux or concentrate heat there (see Fig. 12). Switching from the concentrator +to the cloaking device is achieved by an electric-field-driven bistable anchoring with dye- +doped mematics (sufficiently high values of the electrical potential difference between the +two sides of the hollow cylinder were indeed shown to induce stable anchoring transitions +between homeotropic and parallel states [217]). To avoid thermoconvective instabilities in +the annulus domain, the device must be thin enough and the heat flux and temperature levels +must be moderate. For instance, using 5CB and MBBA, if the temperature is about a few +tens of degrees (thermoelectric applications) and the external radius of a few centimeters, +the device handles heat flux that typically varies from 5 W/m2 (repeller) to 103 W/m2 +(concentrator). +b. +Thermal diodes +The previous study is now refined in order to investigate thermal +rectification. Thermal rectification is a very active subject in nanoscience and solid-state +physics, as testified by the abundant litterature dealing with this subject (extensive reviews +treating thermal rectification can be found in [218, 219]. More seldomly is heat conduction +rectification considered from soft-matter-based devices. In liquid crystals, the macroscopic +thermal properties of the nematic phase depend on temperature according to Haller’s ap- +proximation [220]: +λ∥(T) = λ0 + λ1 × (T − TNI) + λ1∥ × (T − TNI)α∥ +(20) +λ⊥(T) = λ0 + λ1 × (T − TNI) + λ1⊥ × (T − TNI)α⊥ +(21) +where λ0, λ1, λ1∥, λ1⊥, α∥ and α⊥ are material-depending constants, whereas TNI and TC +are, respectively, the nematic-to-isotropic temperature and the clearing-point temperature +of the liquid crystal. As discussed before, liquid crystals naturally provide a stable and +flexible configuration corresponding to such asymmetry, the ERD, which already turns out +to provide high levels of acoustic rectification. To achieve high rectification levels, the same +38 + +conical frustum of varying radius R(z) with anchoring conditions can be used. In analogy +with the acoustic case discussed earlier, the rectification parameter used to estimate the +thermal diode efficiency can be defined as +Thermal rectification(%) = +���� +∆Ti − ∆Td +∆Td +���� × 100 +(22) +where ∆Td = Td,h − T0 is the difference between Td,h, the high temperature on one base +produced by the heat pumped in the cylinder when working in the direct setup (i.e. when +the heat is flowing from the narrow region to the wider one, i.e. the −z direction), and +T0, the temperature at the other base, which is also the initial temperature. +Similarly, +∆Ti = Ti,h − T0 when working in the inverse setup. +Numerical simulations show thermal rectification rates around 1266% [221]. On the shape +parameters, alterations on the ratio Rr ∈ [0, 28; 0, 75] produced a percentage variation on +the thermal rectification around 1273%, while modifications of the height h ∈ [50; 75] µm +and on the larger radius Rl ∈ [50; 70] µm produced percentage changes lower than 5%. +This indicates that the anisotropy of the conical frustum tube has a strong influence on the +rectification. Other non-geometrical parameters such as the anchoring angle (in the range +[0; 90◦]) and the inward pumped heat flux (in the range [5; 10] kW/m2) give percentage +variations on the rectification around, respectively, 3, 8 and 1, 7%. +Such characteristics +enable this improved thermal diode to be miniaturized, applied on well-determined areas, +while robust against variations of the inward pumped heat flux. +The identical forms of the geometry experienced by light and by sound strongly suggests +that devices using liquid crystals may be used to manipulate simultaneously optical and +thermodynamical transport. Indeed, Ref. [222] reports the control of both electromagnetic +propagation and heat flow by a liquid crystal device similar to the one depicted in Fig. 12, +while Ref. [223] uses an escaped disclination configuration to rectify at the same time both +heat and light, thus a thermo-optical diode. +V. +CONCLUSION AND PERSPECTIVES +Since their early discovery in the XIXth century, liquid crystals have been the magic bullet +in physics and engineering. Being in-between anisotropic solids and isotropic fluids, they +extended our conception of condensed matter to an area where geometry and topology can +39 + +FIG. 13. Left: Isothermal surfaces of a liquid crystalline thermal diode in (up) inverse thermal +setup and (bottom) direct thermal setup. The frustum diode has larger radius Rl = 70 µm, ratio +between the radii is Rr = Rsm/Rl = 0, 28, the height is h = 50 µm, anchoring is 60◦ and the +inward heat flux is Q = 5 kW/m2 on the base with the higher temperature and T0=296 K. Right: +Rectification rate versus temperature T0 of the base for different larger radii Rl. Taken from [179]. +be almost as useful as in General Relativity. An orientationally ordered fluid, as the nematic +liquid crystal, is a vivid representation of a Riemannian manifold where the director field +can be associated to a local vector basis (triad or dreibein). The relative rotation of the +director/triad associated to neighboring points indicates the presence of curvature. Bound- +ary conditions like vessel shape, immersed objects, anchoring angle, etc., impose restrictions +to the effective geometry whose eventual incompatibility with the nematic order (ground +state or zero curvature everywhere) leads to the appearance of topological defects which +accommodate the incompatibilities. +This geometric view of the elastic distortions in the NLC is complemented by the optical +effective geometry that appears naturally by comparing Fermat’s law of least time to the +geodesic variational principle. Similar effective geometries can be obtained for acoustics +and heat transport as well. In all these cases the defects, besides being the consequence of +40 + +μm + 309 +0 +308.58 +306.77 +307.67 +40 +305.87 +304.97 +304.06 +303.16 +20 +1.270 +301.35 +0 +7 300 +1.260 +-50 +0 +50 +Rectification [%] +1.250 +R, = 50 μm +R; = 57 jm +R; = 63 jm +1.240 - +R=70m +μm + 301 +1.230 +300.64 +300.57 +1.220 +40 +300.5 +300.44 +300.37 +1.210 +300.3 +295 +296 +297 +298 +299 +300 +TOE +20 +300.23 +300.17 +Te [K] +300.1 +0 +300.03 +V 300 +-50 +0 +50the topology (boundary conditions), are the source of the geometry. One might then say +that, as soon as there is real or effective curved geometry to describe a physical system with +orientational order, one can expect defects. And, if there is curved geometry, one can relate +NLC to gravitation and cosmology. In this article we reviewed, not only this relationship, +but also the physical applications obtained with the help of the geometric tools. +Many +open problems both in gravitation and cosmology and in NLC certainly may benefit from +the analogies derived by the (partially) common geometry. For instance, the experimental +knowledge about the inner structure of disclinations may be an inspiration for cosmic string +core models. Active matter, being a dynamic medium, may be described by time-depending +metrics. Furthermore, being a dissipative medium, active matter (or its effective geometry) +might obey a geometric flow like Ricci’s [224] in its way to the equilibrium. +ACKNOWLEDGMENTS +For the purpose of Open Access, a CC-BY public copyright licence, +, has been +applied by the authors to the present document and will be applied to all subsequent versions +up to the Author Accepted Manuscript arising from this submission. +[1] Pierre Gilles de Gennes. 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